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    3. Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds (Repost)

    Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds (Repost)

    Posted By: DZ123
    Date: 17 Apr 2020 19:34:04
    Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds (Repost)

    Stacey L. McDonald, "Copper-Catalyzed Electrophilic Amination of sp2 and sp3 C−H Bonds"
    English | 2016 | ISBN: 3319388770 | PDF | pages: 162 | 7.1 mb

    This thesis reports the latest developments in the direct amination of various C−H bonds using an H−Zn exchange/electrophilic amination strategy.  McDonald and co-workers reveal this approach to be a rapid and powerful method for accessing a variety of functionalized amines.
    The material outlined in this book shows how McDonald achieved C−H zincation using strong, non-nucleophilic zinc bases and subsequent electrophilic amination of the corresponding zinc carbanions with copper as a catalyst and O-benzoylhydroxylamines as the electrophilic nitrogen source.
    McDonald’s findings are of relevance to medicinal chemistry, drug discovery and materials science. Her thesis is a source of inspiration for scientists entering the field and students beginning their PhD in a related area.
    UPWARDS